The eight new members - five Greens, one Labor and two Liberals - will give their inaugural speeches on Wednesday or Thursday.

The front bench will for the first time feature three Greens ministers.

Three government bills will be introduced, including amendments to the COVID-19 emergency response bill.

The government will also introduce its Plastic Reduction Bill which would outlaw certain single use plastics.

Plastic stirrers, cutlery and polystyrene takeaway containers are all set to be banned by July next year.

Opposition health spokeswoman Giulia Jones will move a motion to support junior doctors facing high levels of burnout and stress.

The motion comes after an internal report revealed Canberra's trainee doctors were facing a disproportionately high fail rate due to concerning levels of burnout and poor workplace culture.

It found doctors have worked unsafe hours and their enterprise bargaining agreement had been breached.

Just 37 per cent of trainee physicians passed their clinical exams in 2019, well below the Australian average of 70 per cent.

There were several "concerning" stories about coercion to come to work despite requesting sick leave, with trainees told the system was desperate and not able to cover their absence.

It will be the first sitting since the ACT Greens tripled their representation in the Assembly after a strong showing, gaining 13.5 per cent of the popular vote, at the October election.

The Greens gave their support to Labor to form a minority government.

Greens Leader and Attorney-General Shane Rattenbury said the party was excited to get to work.

"The new members are excited to actually get into the chamber after many weeks of preparing and getting ready," he said.

"They are all looking forward to giving their first speeches as a chance to spell out what got them.

"It's not a heavy program outside of those first speeches."

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