Police have found 21 grams of the drug ice and 20 grams of heroin after they stopped a vehicle travelling near Goulburn.
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A man and a woman, one of whom is believed to be from the ACT, were found in possession of the drugs after police stopped a Mitsubishi Mirage on the Hume Highway.
Police pulled over the 23-year-old woman and her male passenger, 35, at about 11pm on Friday.
The female driver underwent a roadside drug test which gave a positive result. Officers searched the vehicle and located the methamphetamine, commonly known as ice, and heroin.
The pair was arrest on charges of drug supply, and they were refused bail. They will face Goulburn Local Court on Tuesday.
Traffic and highway patrol command's assistant commissioner Michael Corboy said this arrest was proof that training continued to deliver both road safety and crime reduction results for the community.
"Those using our highways to commit crime have been put on notice and can expect to be intercepted by traffic and highway patrol command officers, " he said.
Investigations are ongoing.
